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Record W2051073622 · doi:10.1021/cm7028905

Optical Enhancing Properties of Anisotropic Gold Nanoplates Prepared with Different Fractions of a Natural Humic Substance

2008· article· en· W2051073622 on OpenAlexaff
Roberto Baigorri, José María García‐Mina, Ricardo F. Aroca, Ramón A. Álvarez‐Puebla

Bibliographic record

VenueChemistry of Materials · 2008
Typearticle
Languageen
FieldMaterials Science
TopicGold and Silver Nanoparticles Synthesis and Applications
Canadian institutionsUniversity of Windsor
Fundersnot available
KeywordsMaterials scienceNanostructureRaman scatteringRaman spectroscopyPlasmonColloidal goldSubstrate (aquarium)NanotechnologySurface plasmon resonanceSuspension (topology)NanoparticleChemical engineeringHumic acidChemistryOptoelectronicsOrganic chemistryOptics

Abstract

fetched live from OpenAlex

The results of this work demonstrate the properties of suspensions of humic substances (HS) used as reducing and templating agent for the formation of gold nanostructures. It is further established that a considerable degree of control over the size and shape of the nanoparticles can be achieved by selecting the appropriate humic fraction and adjusting the pH of the working suspension. These gold nanostructures can sustain surface plasmon resonances and exhibit optical enhancing properties that make them suitable for plasmonic applications and optical enhancement such as surface-enhanced Raman scattering (SERS). The efficiency of the nanostructures as a SERS substrate is illustrated enhancing the Raman spectrum of 2-mercaptobenzothiazole (MBT), a common organic pollutant.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.001
Threshold uncertainty score0.570

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.016
GPT teacher head0.209
Teacher spread0.193 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations46
Published2008
Admission routes1
Has abstractyes

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