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Record W2051372028 · doi:10.1107/s1600536807008057

Tetraphenylphosphonium [<i>N</i>-(2-aminophenyl)-2-(mercaptomethylcarbonylamino)ethanamido(4−)-κ<sup>4</sup> <i>S</i>,<i>N</i>,<i>N</i>′,<i>N</i>′′]oxorhenate(V)

2007· article· en· W2051372028 on OpenAlexaff
Julien Le Gal, Éric Benoist, Marie Gressier, F. Bélanger-Gariépy, André L. Beauchamp

Bibliographic record

VenueActa Crystallographica Section E Structure Reports Online · 2007
Typearticle
Languageen
FieldBiochemistry, Genetics and Molecular Biology
TopicChemical Synthesis and Analysis
Canadian institutionsUniversité de Montréal
Fundersnot available
KeywordsChemistryLigand (biochemistry)DeprotonationCrystallographyIonStereochemistrySquare pyramidal molecular geometryAtom (system on chip)Crystal structure

Abstract

fetched live from OpenAlex

The title compound, (C 24 H 20 P)[Re(C 10 H 9 N 3 O 2 S)O], contains well separated square-pyramidal [ORe L ] − complex anions ( L is the deprotonated N -(2-aminophenyl)-2-(mercaptomethylcarbonylamino)ethanamide ligand) and tetrahedral [(C 6 H 5 ) 4 P] + cations. In the anion, the Re=O bond is oriented along the apical direction and the four basal sites are occupied by one S– and three N-atom donors of the tetradentate L 4− ligand.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: none
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.827
Threshold uncertainty score0.999

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0010.000
Meta-epidemiology (narrow)0.0010.001
Meta-epidemiology (broad)0.0010.001
Bibliometrics0.0010.002
Science and technology studies0.0000.001
Scholarly communication0.0000.000
Open science0.0010.000
Research integrity0.0010.001
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.005
GPT teacher head0.230
Teacher spread0.225 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations1
Published2007
Admission routes1
Has abstractyes

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