Adsorption and Electrosorption of Ethyl Xanthate and Thiocyanate Anions at High-Area Carbon-Cloth Electrodes Studied by in Situ UV Spectroscopy: Development of Procedures for Wastewater Purification
Why this work is in the frame
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Bibliographic record
Abstract
Adsorption and electrosorption behavior of ethyl xanthate (EtX - ) and thiocyanate (SCN - ) anions, individually and when they are together in a solution, were studied at high-area C-cloth electrodes by in situ UV spectroscopy in relation to development of methodologies for purification of industrial wastewaters. The employment of straightforward, yet demonstrably useful spectrophotometric techniques of kinetics and scanning kinetics is described. Adsorption isotherms of EtX - and SCN - were also derived. However, EtX - was found to decompose to a small extent during electrosorption on C-cloth and/or Au or Pt surfaces, causing some interference with the spectrophotometric analysis of SCN - at 215 nm. After long prior contact of the C-cloth with water, the adsorption rates of EtX - and SCN - are somewhat increased. Competitive adsorption studies show that SCN - ion does not become adsorbed on the C-cloth in the presence of EtX -, thus demonstrating a remarkable discriminatory effect.
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Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it