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Record W2053388688 · doi:10.1002/adom.201300437

Highly Efficient Organic Light‐Emitting Devices Prepared with a Phosphorescent Heteroleptic Iridium (III) Complex Containing 7,8‐Benzoquinoline as the Cyclometalated Ligand

2014· article· en· W2053388688 on OpenAlexaff
Frédéric Dumur, Marc Lepeltier, Hossein Zamani Siboni, Didier Gigmès, Hany Aziz

Bibliographic record

VenueAdvanced Optical Materials · 2014
Typearticle
Languageen
FieldEngineering
TopicOrganic Light-Emitting Diodes Research
Canadian institutionsUniversity of Waterloo
FundersAssociation Instituts CarnotCentre National de la Recherche ScientifiqueAix-Marseille Université
KeywordsPhosphorescenceDopantCommon emitterIridiumOLEDLigand (biochemistry)Materials scienceIsoquinolineOptoelectronicsPhotochemistryChemistryNanotechnologyDopingStereochemistryCatalysisOrganic chemistryFluorescenceOpticsPhysics

Abstract

fetched live from OpenAlex

The performance of a heteroleptic bis‐cyclometalated complex based on 7,8‐benzoquinoline ligands is investigated as a new emitter in phosphorescent OLEDs. The devices show very high efficiency at various dopant concentrations and maximum efficiency is achieved at 8% dopant concentration. A comparison of the performance of PHOLEDs with the new emitter versus those with Ir(ppy)3 emitter reveals an improvement of efficiency at all dopant concentrations. These preliminary results obtained with the first bzq‐based emitter indicate that this family of cyclometalated proligands is a promising compound for the development of highly emissive complexes.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.001
Threshold uncertainty score0.004

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0010.000
Open science0.0010.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.007
GPT teacher head0.231
Teacher spread0.224 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations24
Published2014
Admission routes1
Has abstractyes

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