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Record W2053669505 · doi:10.1139/p04-018

Spectroscopic investigation of sensitized-Cs (6<sup>2</sup> <i>P</i><sub>3/2</sub>6<sup>2</sup><i>P</i><sub>1/2</sub>) laser retrofluorescence in a pure optically thick vapour near a dissipative surface

2004· article· en· W2053669505 on OpenAlexafffundvenue
Karine Le Bris, Claude Kondo Assi, Jean Gagné

Bibliographic record

VenueCanadian Journal of Physics · 2004
Typearticle
Languageen
FieldChemistry
TopicSpectroscopy and Laser Applications
Canadian institutionsPolytechnique Montréal
FundersNatural Sciences and Engineering Research Council of Canada
KeywordsPhysicsHyperfine structureAtomic physicsLaserMonochromatic colorExcitationResonance (particle physics)Analytical Chemistry (journal)Spectral linePopulationLine (geometry)Optics

Abstract

fetched live from OpenAlex

A low-power, monochromatic, tunable diode laser is used to selectively populate the cesium 6 2 P 3/2 (F e = 2, 3, 4, 5) hyperfine-structure levels in a pure optically thick vapour in the presence of a dissipative surface. The integrated retrofluorescence intensities for the 852 nm (6 2 P 3/2 → 6 2 S 1/2 ), 894 nm (6 2 P 1/2 → 6 2 S 1/2 )&gt; and 455 nm (7 2 P 3/2 → 6 2 S 1/2 ) lines have been measured and analyzed. When the laser frequency is scanned through the [6 2 S 1/2 (F g ) → 6 2 P 3/2 (F e )] hyperfine resonance line, the sensitized retrofluorescence spectral signal corresponding to the 894 nm line has a profile significantly different from the retrofluorescence signal at the 852 nm line, but rather similar to the profiles of the lines associated with the energy-pooling collisions. The population of the 6 2 P 1/2 atomic level in an optically thick vapour cannot be explained only by the fine-structure excitation transfer process [Cs (6 2 P 3/2 ) + Cs (6 2 S 1/2 ) ↔ Cs (6 2 P 1/2 ) + Cs (6 2 S 1/2 )] usually accepted in an optically thin vapour. We have investigated inelastic collisions in the populating mechanisms of 6 2 P 1/2 level starting from the 6 2 P 3/2 level exited by the monochromatic laser taking into account the presence of an electrically conductive surface. It appears from our experimental and theoretical investigations that, the spectral properties of the laser-induced Cs 894 nm sensitized retrofluorescence in a pure optically thick vapour near a dissipative surface cannot be explained by both the conventional mechanism and cascade collisions. The satisfactory interpretation of the experimental results is an open problem of atomic spectroscopy.PACS Nos.: 32.30, 32.50, 32.70, 32.80, 34.10, 34.50, 42.62

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.095
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0010.000
Meta-epidemiology (narrow)0.0010.001
Meta-epidemiology (broad)0.0010.000
Bibliometrics0.0000.001
Science and technology studies0.0000.001
Scholarly communication0.0000.001
Open science0.0010.000
Research integrity0.0000.002
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.009
GPT teacher head0.220
Teacher spread0.210 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations3
Published2004
Admission routes3
Has abstractyes

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