Predicting Near-Neutral pH SCC Conditions Under a Disbonded Coating on Pipelines
Bibliographic record
Abstract
Cathodic protection (CP) shielding and the presence of carbon dioxide (CO2) in the soil environment are necessary for the occurrence of near-neutral pH stress corrosion cracking (NNPHSCC). Quantitative understanding of the relationship between external conditions, coating deterioration and NNPHSCC is emerging but needs further improvements in modeling and experimental tool. This paper is aimed at understanding the environments initiating the NNPHSCC. New experimental results are presented on crevice chemistry due to the degradation of the mastic of a commercial high-density polyethylene (HDPE) coating and due to CO2 penetration into a disbonded crevice through the coating. Also presented are the results obtained from a comprehensive model, TECTRAN, on the effect of CO2 penetration into a crevice through the holiday alone and through both the holiday and the coating. The experimental results show that as the coating mastic degrades in the soil solution, the solution pH decreases within a few days from about 9 to a steady-state value of about 7.5. The Co2 diffusion through a 0.3 mm commercial HDPE coating is rapid, with a decrease of the soil solution pH from 9 to 5 within a matter of days (external CO2 pressure is 1 atm). The model results show that the presence of CO2 in the soil (0.05 atm partial pressure) can reduce the crevice solution pH to near neutral due mainly to its penetration through the coating, confirming previous hypotheses regarding its role in initiating NNPHSCC.
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How this classification was reachedexpand
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.001 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one teacher head, not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".