TS-1 coated mesocellular titano-silica foams as new catalysts for oxidation of bulky molecules
Bibliographic record
Abstract
TS-1 coated Ti-MCF materials have been prepared by the coating procedure using a diluted clear gel solution containing primary TS-1 nano-crystal units. Various techniques such as BET, TEM, FTIR, 29Si MAS NMR were used to monitor the physico-chemical properties of these samples. The coated samples exhibit higher activity and H2O2 selectivity for 1-naphthol hydroxylation compared to those of the parent Ti-MCF and TS-1 samples. Furthermore, a high hydrothermal stability of the mesopore structure and the absence of any Ti leaching during reaction were observed for the coated samples. This could be due to the zeolitic nature and hydrophobicity of the coated samples mesopore surface.
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How this classification was reachedexpand
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.001 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.001 | 0.001 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one teacher head, not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".