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Record W2055284764 · doi:10.1063/1.3043739

Extended negative glow and “hollow anode” discharges for submillimeter-wave observation of CN−, C2H−, and C4H−

2008· article· en· W2055284764 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.
fundA Canadian funder is recorded on the work.

Bibliographic record

VenueThe Journal of Chemical Physics · 2008
Typearticle
Languageen
FieldChemistry
TopicMolecular Spectroscopy and Structure
Canadian institutionsUniversity of Waterloo
FundersNatural Sciences and Engineering Research Council of CanadaUniversity of Waterloo
KeywordsAnodeSubmillimeter waveAnalytical Chemistry (journal)MicrowaveGlow dischargeTorrMillimeterIonChemistryExtremely high frequencyPlasmaAtomic physicsElectrodePhysicsPhysical chemistryOpticsChromatographyOrganic chemistry

Abstract

fetched live from OpenAlex

Three molecular anions, CN(-), C(2)H(-), and C(4)H(-), have been detected in an extended negative glow discharge and a "hollow anode" discharge in the submillimeter-wave region. These electrical discharges have been unexpectedly found to be reasonable anion sources. The measurements have been extended up to 830 GHz, and the molecular constants have been improved significantly compared with those determined by microwave and millimeter-wave spectroscopy. The parent gas mixture of C(2)N(2) or C(2)H(2) of 2 mTorr and Ar or Ne buffer of 15 mTorr was used for the production of CN(-) or C(2)H(-) and C(4)H(-). The number densities of the anions in the cell were estimated to be approximately 1x10(9), approximately 3x10(7), and approximately 3x10(6) cm(-3) for CN(-), C(2)H(-), and C(4)H(-), respectively.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.047
Threshold uncertainty score0.336

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.024
GPT teacher head0.241
Teacher spread0.217 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it