Potentiodynamic Polarization of Platinum and Aluminum in AlCl3-[P14,6,6,6]Cl Melts
Bibliographic record
Abstract
Ionic liquids (ILs) are being considered for a wide range of applications including as a medium for the electrowinning and refining of reactive metals such as aluminium. The electrochemical characteristics of the aluminum chloride - trihexyl(tetradecyl) phosphonium chloride (AlCl3-[P14,6,6,6]Cl) system are explored in this paper. Cyclic voltammograms using a platinum working electrode are presented over a wide range of AlCl3 concentrations (XAlCl3 = 0, 0.3, 0.5, 0.6, 0.67 mole fraction). The potentiodynamic polarization of aluminum were measured in the XAlCl3 = 0.67 melt at 323, 355, 375, 402 and 423 K. The [P14,6,6,6]Cl used was of commercial purity; one of the main impurities is HCl. The presence of HCl in the melt detracts from the current efficiency of aluminum electrodeposition.
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How this classification was reachedexpand
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one teacher head, not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".