Reversible Passivation of Silicon Dangling Bonds with the Stable Radical TEMPO
Why this work is in the frame
A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.
Bibliographic record
Abstract
TEMPO, 2,2,6,6-tetramethylpiperidinyloxy, was used to passivate dangling bonds on hydrogen-terminated Si(100) and Si(111) surfaces. TEMPO reacts with the dangling bond through a radical coupling reaction of the oxygen and silicon atoms. STM images reveal that the TEMPO-passivated Si is stable under typical imaging conditions and also protects the surface from reaction with styrene. TEMPO may also be desorbed from the surface by scanning at elevated voltages (greater than −3.5 V) and provides the ability to selectively remove TEMPO to prepare single dangling bonds on an otherwise passivated surface.
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Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it