Alkynedicobalt Complexes in γ-Carbonyl Cations and Cycloheptynedicobalt Complexes
Why this work is in the frame
A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.
Bibliographic record
Abstract
This Account describes our work on highly electrophilic γ-carbonyl cations featuring propargyldicobalt cations, cycloheptynedicobalt complexes, and the interconnection between the two systems. 1 Introduction 2 γ-Carbonyl Cations via Iron Allyl Cations 3 γ-Carbonyl Cations via Propargyldicobalt Cations 3.1 Synthesis of Velloziolide 3.2 Synthesis of Microstegiol 4 Synthesis of Cycloheptynedicobalt Complexes 4.1 Synthesis via γ-Carbonyl Cations 4.2 Cycloheptynedicobalt Complexes via [4+3] Cycloaddition Reactions 4.3 Cycloheptynedicobalt Complexes via Ring-Closing Metathesis 4.4 Cycloaddition Reactions on Cycloheptynedicobalt Complexes 4.5 Cycloheptynedicobalt Complexes via Intramolecular Nicholas Reactions 5 Dehydrotropylium Ion Co<sub>2</sub>(CO)<sub>6</sub> Complex 6 Final Comments
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Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.003 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it