Tunable electrogenerated chemiluminescence from CdSe nanocrystals
Bibliographic record
Abstract
Electrochemical behavior and related optoelectronic properties of CdSe nanocrystals (NCs) in aprotic solutions have been investigated. NCs of 2.50 ± 0.50 nm diameter were synthesized using a modified procedure in which the temperatures at the time of Se precursor injection and NC growth were controlled. The electrochemical band gap was found to agree with those determined by UV–vis absorption spectroscopy and by the tunneling current-voltage spectrum in the literature. Electrogenerated chemiluminescence of the NCs with peak maxima at 1.90 eV (red, 653 nm) and 2.55 eV (blue, 486 nm) can be generated and altered by scanning the voltage between –1.60 and –1.80 V and between –2.00 and –2.20 V, respectively. The results demonstrate the potential capability of the NCs for light emission tuned by the applied potential.Key words: CdSe nanocrystals, electrochemistry, electrogenerated chemiluminescence, UV–vis spectroscopy, photoluminescence.
Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.
How this classification was reachedexpand
Full frame machine prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.
Distilled classifier scores by category (both heads)
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.001 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".