Etude structurale et spectroscopique de l’apatite : Na<sub>1,69</sub>Pb<sub>8,31</sub>(PO<sub>4</sub>)<sub>5,76</sub>(HPO<sub>4</sub>)<sub>0,24</sub>(OH)<sub>0,55</sub>
Bibliographic record
Abstract
A partir d'une etude radiocristallographique sur poudre cristalline par la methode de Rietveld, nous avons montre que le compose Na 1,69 Pb 8,31 (PO 4 ) 5,76 (HPO 4 ) 0,24 (OH) 0,55 cristallise dans le systeme hexagonal, groupe d'espace P3. Les deux sites cationiques 2x(3d) (notes Pbl et Pb2), equivalents au site (6h) de P6 3 /m, sont totalement occupes par le plomb. Les sites (4f) de P6 3 /m se subdivisent en quatre sites non equivalents 2x(1c) + 2x(1b) dans P3. Trois de ces sites sont occupes a la fois par le sodium et le plomb, alors que le quatrieme est totalement occupe par le plomb. Les spectres de diffusion Raman et IR de ce compose ont ete etudies en detail sur la base de la theorie des groupes et par reference aux autres composes apatitiques. La presence des trois raies, sur le spectre Raman, vers 935, 960 et 973cm -1 et qui sont attribuees aux modes de vibration totalement symetriques v 1 (PO 4 ) confirment bien la baisse de symetrie observee.
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How this classification was reachedexpand
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.009 | 0.004 |
| Meta-epidemiology (narrow) | 0.007 | 0.007 |
| Meta-epidemiology (broad) | 0.006 | 0.003 |
| Bibliometrics | 0.003 | 0.009 |
| Science and technology studies | 0.009 | 0.017 |
| Scholarly communication | 0.006 | 0.009 |
| Open science | 0.009 | 0.005 |
| Research integrity | 0.004 | 0.006 |
| Insufficient payload (model declined to judge) | 0.000 | 0.004 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; both teacher heads agree on what is shown here.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".