MétaCan
Menu
Back to cohort
Record W2056871417 · doi:10.1107/s0108767302099464

New gas hydrate structures

2002· article· en· W2056871417 on OpenAlexaff
J. S. Loveday, R. J. Nelmes, M. Guthrie, D. D. Klug, J. S. Tse

Bibliographic record

VenueActa Crystallographica Section A Foundations of Crystallography · 2002
Typearticle
Languageen
FieldEnvironmental Science
TopicMethane Hydrates and Related Phenomena
Canadian institutionsSteacie Institute for Molecular Sciences
Fundersnot available
KeywordsClathrate hydrateHydrateChemistryOrganic chemistry

Abstract

fetched live from OpenAlex

We have developed high-temperature techniques to measure in situ neutron powder diffraction and synchrotron x-ray powder diffraction. The new furnace for high-temperature neutron diffraction study does not yield any extra peaks due to heaters and refractory, thus we are able to easily measure very small neutron peaks from the sample. Quality neutron-diffraction data at high temperatures up to 1600C were analyzed by Rietveld method for various materials as calcium titanate, yttrium tantalate and silicon nitride. The tilting of Ti-O octahedra was found to be the key to understand the phase transitions in the calcium titanate. The high-resolution synchrotron X-ray diffraction enabled to determine exactly the unit-cell parameters around a phase transition point and the phase transition temperatures of perovskite-related materials as A-site deficient lanthanum titanate and barium titanate. The axial ratio b/a of orthorhombic lanthanum titanate continuously decreased with an increase of temperature.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow), Insufficient payload (model declined to judge)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Not applicable · Consensus signal: none
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.868
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0010.003
Science and technology studies0.0000.001
Scholarly communication0.0000.001
Open science0.0010.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0260.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.012
GPT teacher head0.219
Teacher spread0.207 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

Study designNot applicable
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations2
Published2002
Admission routes1
Has abstractyes

Explore more

Same venueActa Crystallographica Section A Foundations of CrystallographySame topicMethane Hydrates and Related PhenomenaFrench-language works237,207