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Record W2057059246 · doi:10.1039/c2jm15014j

Titanium nitride–carbon nanotube core–shell composites as effective electrocatalyst supports for low temperature fuel cells

2012· article· en· W2057059246 on OpenAlex
Drew Higgins, Ja‐Yeon Choi, Jason Wu, Anand Lopez, Zhongwei Chen

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.
fundA Canadian funder is recorded on the work.

Bibliographic record

VenueJournal of Materials Chemistry · 2012
Typearticle
Languageen
FieldEnergy
TopicElectrocatalysts for Energy Conversion
Canadian institutionsUniversity of Waterloo
FundersNatural Sciences and Engineering Research Council of CanadaMcMaster University
KeywordsElectrocatalystTinMaterials scienceThermogravimetric analysisTitanium nitrideCarbon nanotubeNanocompositeCatalysisTitaniumChemical engineeringNanotechnologyNitrideComposite materialElectrochemistryElectrodeChemistryMetallurgyLayer (electronics)Organic chemistryPhysical chemistry

Abstract

fetched live from OpenAlex

Titanium nitride–carbon nanotube (TiN–CNT) core–shell nanocomposites were developed by a simplistic two step fabrication procedure and characterized by transmission electron microscopy, X-ray diffraction and thermogravimetric analysis. These materials were utilized as platinum nanoparticle electrocatalyst supports (Pt/TiN–CNT) for the oxygen reduction reaction (ORR) and methanol oxidation reaction (MOR), two important low temperature fuel cell processes. Improved ORR and MOR activities were demonstrated for Pt/TiN–CNTs compared with state of the art commercial Pt/C. Moreover, enhanced CO tolerance towards the MOR was demonstrated attributed to the interaction occurring between adsorbed CO molecules and the TiN–CNT supports. TiN–CNTs are thus presented as highly promising, novel electrocatalyst support materials with enhanced ORR and MOR performance attributed to their anisotropic morphology, enhanced electronic properties and conductivity, and distinct catalyst–support interactions.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.002
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0010.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0010.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.004
GPT teacher head0.210
Teacher spread0.206 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it