Monofluorination of Organic Compounds: 10 Years of Innovation
Bibliographic record
Abstract
ADVERTISEMENT RETURN TO ISSUEPREVReviewNEXTMonofluorination of Organic Compounds: 10 Years of InnovationPier Alexandre Champagne, Justine Desroches, Jean-Denys Hamel, Mathilde Vandamme, and Jean-François Paquin*View Author Information Canada Research Chair in Organic and Medicinal Chemistry, CGCC, PROTEO, Département de Chimie, Université Laval, 1045 Avenue de la Médecine, Québec (QC), Canada G1V 0A6*E-mail: [email protected]Cite this: Chem. Rev. 2015, 115, 17, 9073–9174Publication Date (Web):April 9, 2015Publication History Received17 December 2014Published online9 April 2015Published inissue 9 September 2015https://pubs.acs.org/doi/10.1021/cr500706ahttps://doi.org/10.1021/cr500706areview-articleACS PublicationsCopyright © 2015 American Chemical SocietyRequest reuse permissionsArticle Views27866Altmetric-Citations766LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated. Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InRedditEmail Other access optionsGet e-Alertsclose SUBJECTS:Anions,Halogenation,Hydrocarbons,Reaction products,Stereoselectivity Get e-Alerts
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How this classification was reachedexpand
Full frame machine prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.
Distilled classifier scores by category (both heads)
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.014 | 0.006 |
| Meta-epidemiology (narrow) | 0.001 | 0.001 |
| Meta-epidemiology (broad) | 0.001 | 0.001 |
| Bibliometrics | 0.002 | 0.001 |
| Science and technology studies | 0.001 | 0.001 |
| Scholarly communication | 0.006 | 0.007 |
| Open science | 0.002 | 0.004 |
| Research integrity | 0.003 | 0.005 |
| Insufficient payload (model declined to judge) | 0.038 | 0.028 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".