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Record W2057532608 · doi:10.1021/je060420p

Excess Molar Enthalpies of<i>p</i>-Cymene + α-Pinene + β-Pinene at (298.15, 308.15, and 318.15) K and at Atmospheric Pressure

2007· article· en· W2057532608 on OpenAlexaff
Dankui Liao, Xuelin Meng, Zhangfa Tong, Danxing Zheng, Ding‐Yu Peng, Benjamin C.‐Y. Lu

Bibliographic record

VenueJournal of Chemical & Engineering Data · 2007
Typearticle
Languageen
FieldChemistry
TopicChemical Thermodynamics and Molecular Structure
Canadian institutionsUniversity of SaskatchewanUniversity of Ottawa
FundersGuangxi University
KeywordsPineneAtmospheric pressureChemistryTernary operationp-CymeneMolar ratioMolarThermodynamicsAnalytical Chemistry (journal)Organic chemistryMeteorologyGeologyPhysics

Abstract

fetched live from OpenAlex

Excess molar enthalpies ( ), measured at (298.15, 308.15, and 318.15) K in a Calvet low-temperature microcalorimeter, are reported for the ternary mixture of p -cymene (1) + α-pinene (2) + β-pinene (3) at atmospheric pressure. The results serve to show that all the experimental values are positive and that they increase with an increase in temperature. In all cases, maximum values were observed in the vicinity of x 1 ≈ 0.5. Furthermore, at constant x 1, the measured values increase as the ratio of x 2 / x 3 increases.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.001
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.005
Threshold uncertainty score0.017

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.001
Meta-epidemiology (narrow)0.0010.000
Meta-epidemiology (broad)0.0010.000
Bibliometrics0.0010.000
Science and technology studies0.0010.001
Scholarly communication0.0000.001
Open science0.0010.000
Research integrity0.0000.001
Insufficient payload (model declined to judge)0.0050.001

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.006
GPT teacher head0.216
Teacher spread0.210 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations9
Published2007
Admission routes1
Has abstractyes

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