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Record W2057916759 · doi:10.1021/ja002733p

Controlling Photoinduced Electron Transfer within a Hydrogen-Bonded Porphyrin−Phenoxynaphthacenequinone Photochromic System

2000· article· en· W2057916759 on OpenAlexaffabout
Andrew J. Myles, Neil R. Branda

Bibliographic record

VenueJournal of the American Chemical Society · 2000
Typearticle
Languageen
FieldMaterials Science
TopicPorphyrin and Phthalocyanine Chemistry
Canadian institutionsUniversity of Alberta
Fundersnot available
KeywordsPhotochromismPorphyrinCitationComputer sciencePhotoinduced electron transferAltmetricsInformation retrievalWorld Wide WebChemistryLibrary scienceNanotechnologyElectron transferMaterials sciencePhotochemistry

Abstract

fetched live from OpenAlex

ADVERTISEMENT RETURN TO ISSUEPREVCommunicationNEXTControlling Photoinduced Electron Transfer within a Hydrogen-Bonded Porphyrin−Phenoxynaphthacenequinone Photochromic SystemAndrew J. Myles and Neil R. BrandaView Author Information Department of Chemistry, University of Alberta Edmonton, AB, Canada T6G 2G2 Cite this: J. Am. Chem. Soc. 2001, 123, 1, 177–178Publication Date (Web):December 14, 2000Publication History Received25 July 2000Revised10 November 2000Published online14 December 2000Published inissue 1 January 2001https://doi.org/10.1021/ja002733pCopyright © 2001 American Chemical SocietyRequest reuse permissionsArticle Views941Altmetric-Citations112LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated. Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InReddit Read OnlinePDF (41 KB) Get e-AlertscloseSupporting Info (1)»Supporting Information Supporting Information SUBJECTS:Irradiation,Molecular structure,Noncovalent interactions,Pyrroles,Quenching Get e-Alerts

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.002
Threshold uncertainty score0.861

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0010.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0010.001
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0010.000
Research integrity0.0000.001
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.008
GPT teacher head0.226
Teacher spread0.218 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations129
Published2000
Admission routes2
Has abstractyes

Explore more

Same venueJournal of the American Chemical SocietySame topicPorphyrin and Phthalocyanine ChemistryFrench-language works237,207