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Record W2058081294 · doi:10.1021/je000089o

Solubility of Methanethiol and Ethanethiol in a Diethanolamine Solution in the Presence of Acid Gases

2000· article· en· W2058081294 on OpenAlexaff
Fang‐Yuan Jou, Alan E. Mather, Heng‐Joo Ng

Bibliographic record

VenueJournal of Chemical & Engineering Data · 2000
Typearticle
Languageen
FieldEngineering
TopicAdvanced Chemical Sensor Technologies
Canadian institutionsUniversity of Alberta
Fundersnot available
KeywordsMethanethiolChemistryEthanethiolDiethanolamineSolubilityAcid gasAlkanolamineAqueous solutionValeric acidInorganic chemistryMethaneOrganic chemistrySulfurAcetic acid

Abstract

fetched live from OpenAlex

The solubility of methanethiol and ethanethiol in an aqueous solution of 35 mass % diethanolamine was measured at 40 °C and 70 °C. Measurements were made in the absence of acid gases, H 2 S and CO 2, with individual acid gases present, and with mixtures of acid gases present. The total pressure of the experiments was 6890 kPa, which was maintained by methane. The partial pressures of the thiols ranged from 0.1 to 15.8 kPa.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.001
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.021
Threshold uncertainty score0.441

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.001
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0010.000
Research integrity0.0000.001
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.023
GPT teacher head0.253
Teacher spread0.230 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations13
Published2000
Admission routes1
Has abstractyes

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