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Record W2059794894 · doi:10.1021/jp903685g

Biomineralization of Fine Selenium Crystalline Rods and Amorphous Spheres

2009· article· en· W2059794894 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.

Bibliographic record

VenueThe Journal of Physical Chemistry C · 2009
Typearticle
Languageen
FieldNursing
TopicSelenium in Biological Systems
Canadian institutionsAcadia UniversityCollege of the North Atlantic
Fundersnot available
KeywordsAmorphous solidX-ray photoelectron spectroscopyHigh-resolution transmission electron microscopyTransmission electron microscopyAqueous solutionMaterials scienceBovine serum albuminScanning electron microscopeCrystallographyChemical engineeringSelected area diffractionCrystallizationNanotechnologyAnalytical Chemistry (journal)ChemistryChromatographyOrganic chemistry

Abstract

fetched live from OpenAlex

A simple aqueous phase method containing a water-soluble carrier protein, bovine serum albumin (BSA), has been presented for the synthesis of well-defined morphologies of nanobiomaterials. BSA has been used as a shape-directing agent to synthesize crystalline Se nanobars (NBs) and amorphous nanospheres in aqueous phase at a relatively low temperature of 85 °C. Na 2 SeO 3 is used as the Se source to achieve nanoselenium following hydrazine reduction. Well-defined multifacet NBs are produced when the amount of Na 2 SeO 3 is at least 6 times greater than that of BSA (on the basis of per residue), while amorphous spheres are formed with nearly a 1:1 ratio. Both morphologies have been fully characterized by field emission scanning electron microscopy (FESEM), high-resolution transmission electron microscopy (HRTEM), energy dispersive X-ray spectroscopy (EDX), X-ray diffraction (XRD), and X-ray photoelectron spectroscopic (XPS) analysis. Results have shown that the shape-directing ability of unfolded BSA helped to achieve the formation of crystalline NBs, while its soft template effect directed the nanosphere formation.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.003
Threshold uncertainty score0.267

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.010
GPT teacher head0.253
Teacher spread0.242 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it