Novel Highly Fluorinated Poly(arylene ether-1,3,4-oxadiazole)s, Their Preparation, and Sensory Properties to Fluoride Anion
Bibliographic record
Abstract
2,5-Bis(pentafluorophenyl)-1,3,4-oxadiazole (FPOx) has been prepared and successfully polymerized with hexafluorobisphenol A (6F−BPA) by means of an aromatic nucleophilic substitution reaction to produce highly fluorinated poly(arylene ether-1,3,4-oxadiazole)s (FPAEOx). The presence of the highly electron-withdrawing oxadiazole (Ox) group in FPOx significantly enhanced the reactivity of the p -fluorine substituents such that the reaction could be completed in only 1−2 h at room temperature in the presence of 4.0 equiv of potassium fluoride (KF). These mild reaction conditions with low reaction temperatures and the use of a mild base effectively prevented side reactions and ensured the formation of polymers with number-average molecular weights up to 64 000 Da free of cross-linking. FPOx itself and this unit in the FPAEOx were found to be capable of selectively binding fluoride anion (F - ) with high affinity, and produced new peaks in UV and fluorescence spectra, which are in new regions and well-isolated from the original peaks of FPOx or the polymer. The intensities of these resulting new peaks corresponded to the fluoride concentrations. All these features make the monomer and the polymer potential candidates for fluoride sensory and enable the detection a high reliability and a high sensitivity to the concentration as low as 0.1 ppm. This sensory system also showed a very high selectivity for detecting F -, displaying no response to other tested anions including Cl -, Br -, ClO 4 -, HSO 4 -, and PF 6 - .
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How this classification was reachedexpand
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one teacher head, not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".