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Record W2060474374 · doi:10.4236/aces.2014.42028

Upgrading of Heavy Crude Oil with W-Zr Catalyst

2014· article· en· W2060474374 on OpenAlexaboutno aff
P. Schacht, Leonardo Díaz, J. Aguilar, S. Ramírez

Bibliographic record

VenueAdvances in Chemical Engineering and Science · 2014
Typearticle
Languageen
FieldChemistry
TopicPetroleum Processing and Analysis
Canadian institutionsnot available
Fundersnot available
KeywordsAsphalteneRefining (metallurgy)API gravityCrude oilCatalysisSynthetic crudeOil refineryPetroleumRaw materialChemistryFuel oilCrackingWaste managementRefineryPulp and paper industryZirconiumSulfurMetallurgyMaterials scienceOrganic chemistryPetroleum engineeringGeologyShale oilEngineering

Abstract

fetched live from OpenAlex

The main problem of new crude oil reserves is the incipient increase of heavy crude oils in the American continent, i.e. USA, Mexico, Canada and Venezuela. These types of crude oils require several treatments before refining. One of these treatments can be hydrocracking. In this petroleum refining process, it is possible to modify the heavy crude oils to light crude oils. In this paper, we try to use hydrocracking to improve the quality of raw heavy crude oil, through some chemical transformations C-H binding rupture using a catalyst containing active metals such as tungsten and zirconium (W-Zr). After the crude oil was hydrocracked in presence of this novel bimetallic catalyst, the hydrocracked products showed lower content of asphaltenes, resins, sulfur and nitrogen. Also positive changes in the viscosity of crude oil measured as a decreasing of this value were observed. The American Petroleum Institute (API) gravity was significantly increased 6 units. Consequently, all these changes confirmed that the upgrading of the heavy crude oil was successful.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.062
Threshold uncertainty score0.286

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.003
GPT teacher head0.212
Teacher spread0.209 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations4
Published2014
Admission routes1
Has abstractyes

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