Luminescence Spectroscopy and Emitting-State Properties of Pd(SCN)<sub>4</sub><sup>2-</sup>in Crystals
Bibliographic record
Abstract
Luminescence from K 2 Pd(SCN) 4, [K(18-crown-6)] 2 Pd(SCN) 4, and (2-diethylammonium N -(2,6-dimethylphenyl)acetamide) 2 Pd(SCN) 4 is observed between 10000 and 14500 cm - 1 (1000 and 690 nm) at temperatures below 100 K. Luminescence lifetimes of up to 4.15 ms are measured at 10 K. The spectra show resolved vibronic progressions with average energy intervals of 278 and 150 cm - 1 . The average Stokes shift determined from the luminescence and excitation spectra is 4100 cm - 1 . Average dimensionless emitting-state distortions Δ of 3.75 and 1.7, corresponding to Huang−Rhys parameters S of 7.0 and 1.5, along the two modes are obtained from calculated luminescence spectra.
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How this classification was reachedexpand
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.001 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one teacher head, not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".