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Record W2060913275 · doi:10.1021/es9905750

UV/H<sub>2</sub>O<sub>2</sub> Treatment of Methyl <i>tert</i>-Butyl Ether in Contaminated Waters

2000· article· en· W2060913275 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.

Bibliographic record

VenueEnvironmental Science & Technology · 2000
Typearticle
Languageen
FieldEnvironmental Science
TopicAdvanced oxidation water treatment
Canadian institutionsWestern University
Fundersnot available
KeywordsMethyl tert-butyl etherGasolineTolueneChemistryEnvironmental remediationDegradation (telecommunications)BenzeneContaminationEnvironmental chemistryEtherPollutantWater treatmentEnvironmental engineeringEnvironmental scienceOrganic chemistry

Abstract

fetched live from OpenAlex

Methyl tert -butyl ether (MTBE) is a pollutant often found in groundwaters contaminated by gasoline spills or from leaking underground storage tanks. The common techniques often used for the remediation of contaminated water are not very effective for MTBE. This study examines the UV/H 2 O 2 advanced oxidation technology to determine its effectiveness in the treatment of MTBE. The degradation of MTBE was found to follow pseudo- first-order kinetics, and hence the figure-of-merit electrical energy per order ( E EO ) is appropriate for estimating the electrical energy efficiency. The E EO values were found to depend on the concentrations of MTBE, H 2 O 2, and other components, such as benzene, toluene, and xylenes (BTX). This study shows that MTBE can be treated easily and effectively with the UV/H 2 O 2 process with E EO values between 0.2 and 7.5 kWh/m 3 /order, depending on the initial concentrations of MTBE and H 2 O 2 . The treatment efficiency of 10 mg L - 1 MTBE is not adversely affected by the presence of low concentrations of BTX (<2 mg L - 1 ). However, the degradation efficiency is significantly decreased at BTX levels greater than 2 mg L - 1 . A kinetic model, based on the initial rates of degradation, provides good predictions of the E EO values for a variety of conditions.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow), Science and technology studies, Insufficient payload (model declined to judge)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.179
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0010.000
Meta-epidemiology (broad)0.0010.000
Bibliometrics0.0000.001
Science and technology studies0.0000.004
Scholarly communication0.0000.001
Open science0.0010.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.002

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.005
GPT teacher head0.207
Teacher spread0.202 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it