MétaCan
Menu
Back to cohort
Record W2061949733 · doi:10.1039/a908785k

New developments in the chemistry of organoantimony and -bismuth rings

2000· review· en· W2061949733 on OpenAlexafffund
H.J. Breunig, Roland Rösler

Bibliographic record

VenueChemical Society Reviews · 2000
Typereview
Languageen
FieldChemistry
TopicSynthesis and characterization of novel inorganic/organometallic compounds
Canadian institutionsDalhousie University
FundersKillam TrustsDeutsche Forschungsgemeinschaft
KeywordsBismuthAntimonyRing (chemistry)ChemistryLigand (biochemistry)Transition metalPolymer chemistryOrganic chemistryCatalysis

Abstract

fetched live from OpenAlex

Novel organoantimony homocycles comprise a three-membered antimony ring, R3Sb3, organoantimony polycycles, R4Sb8, R5Sb7, and transition metal carbonyl complexes with the t-Bu4Sb4 or t-Bu3Sb4 ligand. In this review the use of t-Bu4Sb4 as a source for complexes with the Sb2 or cyclo-Sb3 ligands and the synthesis and characterisation of the first organobismuth monocycles, RnBin (n = 3, 4) are also discussed.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow), Insufficient payload (model declined to judge)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Not applicable · Consensus signal: none
GenreCandidate signal: Review · Consensus signal: Review
Teacher disagreement score0.985
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0010.000
Meta-epidemiology (broad)0.0020.001
Bibliometrics0.0000.001
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0010.000
Research integrity0.0010.001
Insufficient payload (model declined to judge)0.0050.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.043
GPT teacher head0.283
Teacher spread0.240 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

Study designNot applicable
Domainnot available
GenreReview

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations89
Published2000
Admission routes2
Has abstractyes

Explore more

Same venueChemical Society ReviewsSame topicSynthesis and characterization of novel inorganic/organometallic compoundsFrench-language works237,207