Low temperature interface-mineralizing route to hollow CuS, CdS, and NiS spheres
Bibliographic record
Abstract
Submicrometer hollow CuS, CdS, and NiS spheres with diameters between 400 and 1300 nm were successfully prepared through an interface-mineralizing reaction in a NH 3 ·H 2 OCS 2 solution at low temperature. Several techniques were applied to characterize the interesting self-assembled structures. The compositions of the prepared CuS, CdS, and NiS materials were confirmed by X-ray powder diffraction (XRD), the surface atomic ratios and the valence state of ions were examined by X-ray photoelectron energy spectroscopy (XPS), and the morphologies of products by transmission electron microscope (TEM). The optical properties, including absorption and emission, were recorded by UVvis absorption and fluorescence spectroscopy, respectively. In this approach, ethylenediamine (en) was substituted by aqueous ammonia (NH 3 ·H 2 O) to avoid violent reactions with carbon disulfide (CS 2 ). The main advantage to this approach is that both ammonia and CS 2 played multi-functional roles in the assembly of hollow-sphere structures. The reaction sources themselves (CS 2 ) served as the reaction template and required no other templates to support it. The proposed interface-mineralizing mechanism is discussed, and the hollow-sphere structures obtained are envisioned to have applications in area of materials science.Key words: hollow-sphere structure, NH 3 ·H 2 OCS 2 , metal sulfides
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How this classification was reachedexpand
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.004 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one teacher head, not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".