2000 Macromolecular Science and Engineering Award LectureThe versatility of azobenzene polymers
Bibliographic record
Abstract
The well-known transcistrans photoisomerization of azobenzenes produces at least three different kinds of motion in the polymer materials to which the azobenzenes are bound. The first is a photoinduced motion of the azobenzene groups only, and they can align in a selected position with respect to the light polarization. The second is a macroscopic motion of huge amounts of polymeric material, producing surface deformation, and the third is a reorganization of smectic domains in liquid crystalline polymers. These motions and their consequences are briefly discussed in relation to the polymer structure and some possible photonic applications are mentioned.Key words: photoinduced orientation, azobenzene polymers, surface gratings, photonics, thermochromism, photochromism, photorefractivity, photoinduced chirality and switching.
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How this classification was reachedexpand
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.001 | 0.001 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.001 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one teacher head, not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".