Synthesis, Solid-Phase Reaction, and Patterning of Acid-Labile 3,4-Ethylenedioxythiophene-Based Conjugated Polymers
Bibliographic record
Abstract
3,4-Ethylenedioxythiophene (EDOT)-based conjugated polymers bearing tetrahydropyranyl side groups were synthesized. These include poly[(3-(2-(2-tetrahydropyranyloxy)ethyl)thiophene)−(3,4-ethylenedioxythiophene)] (PTHPET−EDOT), and poly[(3-(11-(2-tetrahydropyranyloxy)undecyl)thiophene)−(3,4-ethylenedioxythiophene)] (PTHPUDT−EDOT). PTHPUDT−EDOT exhibits an enhanced stability in its oxidized state and a high optical contrast ratio between its reduced and oxidized states. Despite its rigid-rod nature, PTHPUDT−EDOT undergoes an acid catalytic reaction that leads to the cleavage and complete elimination of the tetrahydropyranyl group. The decrease in solubility of the deprotected polymer allows for the deposition of PTHPUDT−EDOT in a spatially controlled fashion using chemically amplified photolithography and soft lithography.
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How this classification was reachedexpand
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.006 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one teacher head, not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".