Morphology Control of Electrodeposited Zinc from Alkaline Zincate Solutions for Rechargeable Zinc Air Batteries
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Bibliographic record
Abstract
Anomalous electrocrystallization of Zn in alkaline electrolytes is one of the hurdles hindering the development and commercialization of secondary alkaline Zn batteries. The issue stems from the fast electrochemical kinetics of Zn. Pulse deposition enables the use of high peak current densities and overpotentials in short periods of pulse on-time, increases the nucleation rate and improves the deposit morphology. Electrochemical behavior of Zn and effect of pulse parameters including duty cycle and frequency on deposit morphology was studied for electrolytes containing 4, 6 and 9 M KOH. It was shown that in order to attain fine-grain, smooth deposits, small duty cycles and high frequencies are required. Pulse deposition, however, does not improve the morphology in case highly concentrated KOH electrolytes are used.
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Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.001 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it