In-Situ Hot Stage Atomic Force Microscopy Study of Poly(<b>ε</b>-caprolactone) Crystal Growth in Ultrathin Films
Why this work is in the frame
A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.
Bibliographic record
Abstract
Morphologies, growth rates, and melting of isothermally crystallized ultrathin (200−1 nm) poly(ε-caprolactone) (PCL) films have been investigated in real time by atomic force microscopy. The flat-on orientation of the lamellar crystals relative to the substrate was determined by electron diffraction. The truncated lozenge-shaped PCL crystals observed at low undercooling become distorted for films of thicknesses equal to or thinner than the lamellar thickness, which depends on the crystallization temperature but not on the initial film thickness. The melting behavior of distorted crystals differs from that of undistorted ones, and their growth is slower and nonlinear. The crystal growth rate decreases greatly with the film thickness. All these observations are discussed in terms of the diffusion of the polymer chains from the melt to the crystal growth front.
Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it