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Record W2063052297 · doi:10.1051/jp4:20030242

Atmospheric transoformation of elemental mercury upon reactions with halogens

2003· article· en· W2063052297 on OpenAlex
Parisa A. Ariya, A. Ryzhkov

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.

Bibliographic record

VenueJournal de Physique IV (Proceedings) · 2003
Typearticle
Languageen
FieldEnvironmental Science
TopicMercury impact and mitigation studies
Canadian institutionsMcGill University
Fundersnot available
KeywordsMercury (programming language)HalogenEnvironmental chemistryElemental mercuryChemistryRadiochemistryAstrobiologyInorganic chemistryPhysical chemistryOrganic chemistryPhysics

Abstract

fetched live from OpenAlex

Rapid depletions of atmospheric mercury (Hg 0 ) and ozone have recently been observed in several regions of high-and sub-Arctic, as well as Antarctica.There are a large body of ground based and satellite observations implicating the reactions of halogens, during these depletion events.In our laboratory, we have performed extensive kinetic and product studies on the oxidation reactions of elemental mercury with atmospheric oxidants, along with complementary thermochemical studies based on our kinetics and product studies of reactions of gaseous Hg 0 with molecular and atomic halogens.In this study, we incorporated our laboratory data in a chemical box model (MOCCA).Our results on the potential importance of some key molecular and atomic halogen reactions in depletion of mercury within atmospheric boundary layer, will be discussed.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: none
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.421
Threshold uncertainty score0.571

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.001
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.010
GPT teacher head0.234
Teacher spread0.224 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it