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Record W2063302144 · doi:10.1021/ef900125m

Accelerating CO<sub>2</sub> Dissolution in Saline Aquifers for Geological Storage — Mechanistic and Sensitivity Studies

2009· article· en· W2063302144 on OpenAlexafffund
Hassan Hassanzadeh, Mehran Pooladi‐Darvish, David W. Keith

Bibliographic record

VenueEnergy & Fuels · 2009
Typearticle
Languageen
FieldEnvironmental Science
TopicCO2 Sequestration and Geologic Interactions
Canadian institutionsUniversity of Calgary
FundersNatural Sciences and Engineering Research Council of Canada
KeywordsAquiferDissolutionBrineBuoyancySolubilitySupercritical fluidPetroleum engineeringPermeability (electromagnetism)Soil scienceGeologyEnvironmental scienceChemistryGroundwaterGeotechnical engineeringThermodynamics

Abstract

fetched live from OpenAlex

One of the important challenges in geological storage of CO 2 is predicting, monitoring, and managing the risk of leakage from natural and artificial pathways such as fractures, faults, and abandoned wells. The risk of leakage arises from the buoyancy of free-phase mobile CO 2 (gas or supercritical fluid). When CO 2 dissolves into formation brine, or is trapped as residual phase, buoyancy forces are negligible and the CO 2 may be retained with minimal risk of leakage. Solubility trapping may therefore enable more secure storage in aquifer systems than is possible in dry systems (e.g., depleted gas fields) with comparable geological seals. A crucial question for an aquifer system is, what is the rate of dissolution? In this paper, we address that question by presenting a method for accelerating CO 2 dissolution in saline aquifers by injecting brine on top of the injected CO 2 . We investigate the effects of different aquifer properties and determine the rate of solubility trapping in an idealized aquifer geometry. The acceleration of dissolution by brine injection increases the rate of solubility trapping in saline aquifers and therefore increases the security of storage. We show that, without brine injection, only a small fraction (less than 8%) of the injected CO 2 would be trapped by dissolving in formation brine within 200 years. For the particular cases studied, however, more than 50% of the injected CO 2 dissolves in the aquifer as induced by brine injection. Since the energy cost for brine injection can be small (<20%) compared to the energy required for CO 2 compression for a 5-fold increase in dissolution, such reservoir engineering techniques might be viable and practical for accelerating dissolution of CO 2 . The environmental benefit would be to decrease the risk of CO 2 leakage at reasonably low cost.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.373
Threshold uncertainty score0.384

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.032
GPT teacher head0.289
Teacher spread0.257 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations150
Published2009
Admission routes2
Has abstractyes

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