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Record W2063749122 · doi:10.2113/gscanmin.39.1.145

THE COMPRESSIONAL BEHAVIOR OF P4/n VESUVIANITE

2001· article· en· W2063749122 on OpenAlexvenueno aff
M. Tribaudino, Mauro Prencipe

Bibliographic record

VenueThe Canadian Mineralogist · 2001
Typearticle
Languageen
FieldMaterials Science
TopicX-ray Diffraction in Crystallography
Canadian institutionsnot available
Fundersnot available
KeywordsGeologyGeochemistryMaterials science

Abstract

fetched live from OpenAlex

High-pressure in situ powder-diffraction data were collected on a sample of P4/n vesuvianite from Val d’Ala, Piemonte, Italy, between room pressure and 13.2 GPa. No deviation from tetragonal symmetry was found at any pressure. The refined unit-cell parameters show that the highest compressibility is along the c axis [a = 2.00(4)•10–3 GPa–1 and c = 2.42(7)•10–3 GPa–1]. Such behavior, which is inverse to that observed with increasing temperature, is related to weaker bonding along the 4-fold axis owing to the presence of hydrogen bonding and vacancies. A third-order Birch–Murnaghan equation of state was fitted to the retrieved volumes, with V0 = 2859.47(7), KT0 = 125.5(1.3) GPa and K’T0 = 4.8(3). The compressibility of P4/n vesuvianite probably applies to all members of the vesuvianite family.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.001
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.009
Threshold uncertainty score0.018

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.001
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0010.001
Science and technology studies0.0000.001
Scholarly communication0.0000.000
Open science0.0010.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.024
GPT teacher head0.261
Teacher spread0.237 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations8
Published2001
Admission routes1
Has abstractyes

Explore more

Same venueThe Canadian MineralogistSame topicX-ray Diffraction in CrystallographyFrench-language works237,207