Microcalorimetric Study of the Temperature-Induced Phase Separation in Aqueous Solutions of Poly(2-isopropyl-2-oxazolines)
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Bibliographic record
Abstract
The effect of temperature on aqueous solutions of poly(2-isopropyl-2-oxazoline) (PIPOZ) samples of molecular weights ranging from 1900 to 5700 g mol -1 was monitored by turbidimetry, high-sensitivity microcalorimetry (HS DSC), and pressure perturbation calorimetry (PPC) from 10 to 80 °C. The polymers were soluble in cold water and underwent phase separation at T CP ∼ 45−63 °C, depending on their molecular weight. The phase transition was endothermic, with an enthalpy change ranging from 0.36 ± 0.01 to 1.16 ± 0.01 kcal mol -1 . The coefficient of thermal expansion of PIPOZ in water (α pol ), determined by PPC, underwent a sharp increase at the temperature corresponding to the onset of phase transition, reaching a maximum value at T ∼ T CP . Microcalorimetric measurements were carried out with solutions of PIPOZ samples in D 2 O and in aqueous NaCl solutions. The thermodynamic and volumetric changes associated with the phase transition of aqueous PIPOZ solutions are compared to those of aqueous solutions of two related polymers, poly(vinylcaprolactam) and poly( N -isopropylacrylamide) (PNIPAM), a polymer structurally related to PIPOZ that undergoes a phase transition in water at ∼31 °C.
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Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.001 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it