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Lamellae-Nanotube Isomerism in Hydrogen-Bonded Host Frameworks This work was supported by the National Science Foundation (DMR-9908627), in part by the MRSEC Program of the National Science Foundation (DMR-9809364), and the Natural Sciences and Engineering Research Council of Canada (postdoctoral fellowship for K.T.H.).

2001· article· en· W2065206553 on OpenAlexaboutno aff
M.J. Horner, K.T. Holman, Michael D. Ward

Bibliographic record

VenueAngewandte Chemie International Edition · 2001
Typearticle
Languageen
FieldChemistry
TopicMetal-Organic Frameworks: Synthesis and Applications
Canadian institutionsnot available
Fundersnot available
KeywordsFoundation (evidence)Work (physics)NanotechnologyHost (biology)Materials scienceEngineeringMechanical engineeringPolitical scienceBiologyEcology

Abstract

fetched live from OpenAlex

Inclusion compounds based on a flexible hydrogen-bonded sheet of guanidinium ions and sulfonate moieties display lamellar and tubular architectures, depending on the guest and the organic substituent attached to the sulfonate. The observed single-crystal architectures resemble lamellar and hexagonal microstructures in block copolymers and surfactant assemblies.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.006
metaresearch head score (Gemma)0.005
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesScience and technology studies
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.020
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0060.005
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.002
Science and technology studies0.0010.003
Scholarly communication0.0000.000
Open science0.0010.000
Research integrity0.0000.001
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.040
GPT teacher head0.304
Teacher spread0.264 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations72
Published2001
Admission routes1
Has abstractyes

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