Bibliographic record
Abstract
Five distinct species of OCS–hydrogen van der Waals complexes (OCS–orthoH2,–paraH2,–paraD2,–orthoD2, and –HD) have been observed by infrared spectroscopy in the region of the OCS ν1 vibration (≈2062 cm−1) in a pulsed supersonic jet expansion using a tunable diode laser probe. The spectra are those of prolate asymmetric rotors, with observed a-type transitions (ΔK=0), but no b-type transitions (ΔK=±1). The fitted rotational parameters are consistent with structures having intermolecular separations in the range of 3.6–3.8 Å and angles of about 70° between the OCS axis and the hydrogen center of mass. The band origins are slightly red-shifted (−0.05 to −0.20 cm−1) relative to that of the free OCS molecule. The results are of interest due to recent observations of the same complexes trapped in ultracold helium droplets; there is a remarkably close correspondence of the vibrational band origins of the free and trapped species.
Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.
How this classification was reachedexpand
Full frame machine prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.
Distilled classifier scores by category (both heads)
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.003 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".