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Record W2065999909 · doi:10.1098/rsbm.2003.0011

Gerhard Herzberg PC CC. 25 December 1904 – 3 March 1999

2003· article· en· W2065999909 on OpenAlexaffabout
B. P. Stoicheff

Bibliographic record

VenueBiographical Memoirs of Fellows of the Royal Society · 2003
Typearticle
Languageen
FieldChemistry
TopicMolecular Spectroscopy and Structure
Canadian institutionsUniversity of Toronto
Fundersnot available
KeywordsMolecular spectroscopyNobel laureatePhysicsChemistryAstrochemistrySpectroscopyAstrobiologyAstrophysicsInterstellar mediumAstronomyPhilosophyGalaxy

Abstract

fetched live from OpenAlex

Gerhard Herzberg, Nobel Laureate in Chemistry, had broad interests and achieved supreme accomplishments in physics, chemistry and astrophysics. The high points in his research were many. In physics they were the work on atomic hydrogen and helium, and evaluations of energy levels and constants of molecular hydrogen and its isotopes. His determinations of many molecular structures and discoveries of spectra of the free radicals CH 2 and CH 3 , and of the Rydberg molecule H3, were each outstanding contributions in chemistry. In astrophysics, his reproduction in the laboratory of the spectrum of CH + , proving its presence in the interstellar medium, and of spectra of C 3 and H 2 O + and their presence in comets, his observation of the quadrupole spectrum of H 2 and his discovery of hydrogen in the atmospheres of the planets opened up new applications of spectroscopy for our knowledge of the universe. His classic volumes on molecular spectra and molecular structures remain as encyclopaedias of molecular knowledge for all time. And his famous laboratory, the ‘Temple of spectroscopy’, served as a home for hundreds of scientists around the world, and helped to bring Canadian science to international prominence.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesInsufficient payload (model declined to judge)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.119
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.002
Bibliometrics0.0000.000
Science and technology studies0.0000.001
Scholarly communication0.0000.000
Open science0.0010.000
Research integrity0.0010.001
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.006
GPT teacher head0.223
Teacher spread0.218 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations2
Published2003
Admission routes2
Has abstractyes

Explore more

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