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Record W2066658415 · doi:10.1021/ma101348k

Polystyrene-<i>block</i>-poly(<i>n</i>-butyl acrylate)-<i>block</i>-polystyrene Triblock Copolymer Thermoplastic Elastomer Synthesized via RAFT Emulsion Polymerization

2010· article· en· W2066658415 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.

Bibliographic record

VenueMacromolecules · 2010
Typearticle
Languageen
FieldChemistry
TopicAdvanced Polymer Synthesis and Characterization
Canadian institutionsMcMaster University
FundersNational Natural Science Foundation of China
KeywordsCopolymerPolystyreneMaterials sciencePolymer chemistryThermoplastic elastomerChain transferEmulsion polymerizationUltimate tensile strengthRaftAcrylatePolymerizationRadical polymerizationPolymerComposite material

Abstract

fetched live from OpenAlex

A series of well-controlled polystyrene- b -poly( n -butyl acrylate)- b -polystyrene triblock copolymers were prepared by emulsion polymerization with a carefully designed amphiphilic macroRAFT (reversible addition−fragmentation chain transfer) agent. The triblock copolymers were produced within four hours and only a few percent of dead chains were estimated. Tensile strength of the materials was a function of composition only and it increased linearly with polystyrene composition up to 50 wt %. The ultimate tensile strength reached 10 MPa with an elongation at break of 500% at the polystyrene composition of 40−50 wt %.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow), Insufficient payload (model declined to judge)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.030
Threshold uncertainty score0.999

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0010.001
Meta-epidemiology (broad)0.0010.001
Bibliometrics0.0000.001
Science and technology studies0.0010.000
Scholarly communication0.0000.001
Open science0.0010.000
Research integrity0.0010.001
Insufficient payload (model declined to judge)0.0030.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.004
GPT teacher head0.212
Teacher spread0.208 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it