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Record W2067258741 · doi:10.1139/v00-111

Densities, refractive indices and excess properties of mixing of the <i>n</i>-octanol + 1,4-dioxane + 2-butanol ternary system at 298.15 K

2000· article· en· W2067258741 on OpenAlexvenueno aff
Alberto Camacho, Miguel Postigo, Graciela C. Pedrosa, Inés L. Acevedo, Miguel Katz

Bibliographic record

VenueCanadian Journal of Chemistry · 2000
Typearticle
Languageen
FieldChemical Engineering
TopicThermodynamic properties of mixtures
Canadian institutionsnot available
Fundersnot available
KeywordsChemistryTernary operationRefractive index1,4-DioxaneButanolOctanolBinary numberMixing (physics)ThermodynamicsTernary numeral systemAnalytical Chemistry (journal)ChromatographyOrganic chemistryPartition coefficientEthanolOpticsPhase (matter)

Abstract

fetched live from OpenAlex

Excess molar volumes and excess refractive indices of the n-octanol + 1,4-dioxane + 2-butanol system and the three corresponding binary mixtures have been determined at 298.15 K by measuring densities and refractive indices. Different expressions exist in the literature to predict these excess properties from binary data. An estimation of excess molar volumes is also evaluated using a modified Heller equation which depends on the refractive indices of the mixtures. A comparison of the predictions of different methods with the experimental values of the physical properties has been made.Key words: excess molar volumes, densities, refractive indices, n-octanol, 1,4-dioxane, 2-butanol, ternary system.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.008
Threshold uncertainty score0.550

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0010.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.005
GPT teacher head0.157
Teacher spread0.152 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations5
Published2000
Admission routes1
Has abstractyes

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