Potassium adsorption characteristics and potassium forms in some New South Wales soils in relation to early senescence in cotton

The occurrence of premature senescence (PS) in cotton in Australia has been related to decreased potassium (K) concentration in the affected plants. Soil samples (0–120 cm) were taken from paired cotton fields, i.e. PS fields and similar soils not affected by PS (Non-PS fields), in northern New South Wales. The samples were analysed for different forms of K in soil, mineralogy of various size fractions, and K adsorption characteristics to evaluate differences in their K availability. Smectite was the dominant clay mineral in the studied soils. The K-bearing mineral illite was present in the clay fraction of all samples and its content was generally higher in soils from the Non-PS sites than the PS sites from Moree, Pilliga, and Warren. Water-soluble K (H2O-K) ranged from 0.03 to 2.64 mg/kg (median 0.35 mg/kg), exchangeable K (Exch-K) from 43 to 687 mg/kg (median 107 mg/kg), non-exchangeable K (Nonexch-K) from 164 to 1981 mg/kg (median 819 mg/kg), and total K (Total-K) from 16 811 to 23 207 mg/kg (median 14 740 mg/kg). The values of various K forms were generally higher in samples from the Non-PS fields than the PS fields from Pilliga and Warren sites and the reverse trend occurred for the samples from Trangie. Similar H2O-K and Exch-K values were found for the PS and Non-PS samples from Moree, whereas Nonexch-K and Total-K contents were higher in the top 60 cm soil depth from the Non-PS field than the PS field. The equilibrium activity ratio (ARKe) values were significantly higher for surface samples from the Non-PS sites than the PS sites from Pilliga and Warren and the reverse was true for the Trangie site. There was a sharp decrease in ARKe with depth for the studied samples. The potential buffering capacity (PBCK) for both surface and subsurface samples from the Non-PS site (mean 31.5 (mmol/kg)/(mol/L)1/2) from Trangie was substantially higher than the corresponding samples from the PS sites (mean 14.7 (mmol/kg)/(mol/L)1/2). There was a significant increase in K adsorption for the subsurface samples than the surface samples for all sites, as indicated by the higher values of Freundlich adsorption coefficient, k. At the Pilliga and Warren sites, the occurrence of premature senescence in cotton plants can be explained on the basis of differences in the levels of different forms of K, mineralogy, and K adsorption characteristics of soils from the PS and Non-PS fields. At the Moree site, higher illite content in the Non-PS than the PS soil may explain the difference in their K availability. For the paired Trangie samples, greater PBCK of the Non-PS soil than the PS soil may be responsible for increased K availability in the Non-PS soil. The occurrence of PS symptoms in cotton at Narrabri site cannot be directly contributed to K supplying parameters analysed in the study. The results also show that Exch-K alone may not be adequate to measure K availability to cotton in these soils.

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