The Quest for a Fundamental Algorithm in X-Ray Fluorescence Analysis and Calibration
Why this work is in the frame
A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.
Bibliographic record
Abstract
The Fundamental Algorithm between concentration (C i ) and intensity (R i ) in X-ray fluorescence analysis is deduced from Sherman's equation without any approximation. Its explicit expression is thus theoretically exact and it corrects completely for all matrix effects on the intensity R i emitted by the analyte i in a given specimen. This powerful algorithm combines the practical flexibility of the influence coefficient concept and the theoretical exactness of the Fundamental-Parameters method. In association with its innovative calibration procedure, the Fundamental Algorithm can be applied to the analysis of any sample type and offers maximum accuracy, limited only by the quality of sample preparation and the standards used.
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Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.001 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.001 |
| Science and technology studies | 0.001 | 0.000 |
| Scholarly communication | 0.002 | 0.001 |
| Open science | 0.001 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it