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Record W2067849750 · doi:10.1021/ie8009796

Kinetics of Canola Oil Transesterification in a Membrane Reactor

2009· article· en· W2067849750 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.
fundA Canadian funder is recorded on the work.

Bibliographic record

VenueIndustrial & Engineering Chemistry Research · 2009
Typearticle
Languageen
FieldEngineering
TopicBiodiesel Production and Applications
Canadian institutionsUniversity of Ottawa
FundersNatural Sciences and Engineering Research Council of CanadaFord Foundation
KeywordsTransesterificationMethanolBiodieselMembrane reactorDiesel fuelBatch reactorChemistryBiodiesel productionChemical engineeringCatalysisReaction rateReaction rate constantMembraneVegetable oil refiningOrganic chemistryKineticsBiochemistry

Abstract

fetched live from OpenAlex

Biodiesel is quickly gaining attention as a renewable and environmentally friendly replacement for petroleum-based diesel. The dominant process involved in its production is transesterification consisting of three consecutive reversible reactions. For this work, the transesterification of canola oil was conducted using a continuous membrane reactor in the presence of NaOH as a catalyst. The forward and reverse rate constants of all three steps involved in the transesterification in the membrane reactor are reported. The proposed mathematical model fitted the experimental results well. It was found that increasing the catalyst concentration increased the reaction rates and the residence time did not have a significant influence on the reaction rates. Runs were performed at 0.05, 0.1, and 0.5 wt % NaOH based on the oil. A mole ratio of 24:1 methanol/oil was used in this work. The forward rate constants were greater than previously reported for a batch process. This was attributed to the excellent mixing in the membrane reactor loop, the higher methanol/oil mole ratio used here, and the continuous removal of product from the reaction medium. The advantages of using a membrane rector to enhance the reaction rate in the transesterification of canola oil in a membrane reactor were clearly shown.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.015
Threshold uncertainty score0.544

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.001
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.001
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.093
GPT teacher head0.309
Teacher spread0.216 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it