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Record W2068983291 · doi:10.1246/bcsj.74.187

Characterization of Calcium, Strontium, Barium and Lead Hydroxyapatites: X-ray Diffraction, Photoelectron, Extended X-ray Absorption Fine Structure and MAS NMR Spectroscopies

2001· article· en· W2068983291 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.

Bibliographic record

VenueBulletin of the Chemical Society of Japan · 2001
Typearticle
Languageen
FieldMaterials Science
TopicX-ray Diffraction in Crystallography
Canadian institutionsUniversity of Waterloo
Fundersnot available
KeywordsChemistryHydroxyapatitesBariumX-rayStrontiumX-ray crystallographyCharacterization (materials science)CrystallographyCalciumInorganic chemistryDiffractionNanotechnologyOrganic chemistry

Abstract

fetched live from OpenAlex

Abstract Calcium, strontium, barium and lead hydroxyapatites have been investigated by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), extended X-ray absorption fine structure (XAFS) and solid state NMR. XPS analyses showed that the binding energies of P 2s or P 2p and O 1s of all hydroxyapatites, XRD of which matched to the corresponding JCPDS data, were essentially identical and were not influenced by those divalent cations. In contrast, it was revealed that the nearest neighbour distances between divalent cations and oxygen determined by XAFS and the chemical shifts of 1H and 31P NMR were strongly influenced by each divalent cation in hydroxyapatites.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.126
Threshold uncertainty score0.768

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.001
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.008
GPT teacher head0.217
Teacher spread0.209 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it