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Record W2070116506 · doi:10.1201/9780203742815-6

Hydrogels Based on Polysaccharides

2017· book-chapter· en· W2070116506 on OpenAlexaff
Severian Dumitriu, P. F. Vidal, E. Chornet

Bibliographic record

Venuenot available
Typebook-chapter
Languageen
FieldBiochemistry, Genetics and Molecular Biology
TopicHydrogels: synthesis, properties, applications
Canadian institutionsUniversité de Sherbrooke
Fundersnot available
KeywordsChemistryPolysaccharideSelf-healing hydrogelsPolymer scienceNanotechnologyPolymer chemistryOrganic chemistry

Abstract

fetched live from OpenAlex

Gels are cross-linked networks of polymers swollen with a liquid. Two-thirds of the human body consists of water, and almost all known biological reactions occur in water. The ability of polysaccharides to form a network structure, even at very low concentrations, constitutes one of their most important functional properties. Many natural and bacterial polysaccharides, charged or uncharged, form three-dimensional networks under specific conditions. Cross-linking is one of the oldest methods for the chemical modification of polymers. Various degrees of cross-linking can be introduced into polysaccharides for the purpose of generating larger molecular aggregates with enhanced viscosity profiles, or for the preparation of insoluble products with a wide range of swelling characteristics. Reaction of polysaccharides with epichlorohydrin usually leads to cross-linking, but monofunctional side reactions may also occur to form a series of by-products with glycolic functional groups.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow), Insufficient payload (model declined to judge)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: none
GenreCandidate signal: Other · Consensus signal: Other
Teacher disagreement score0.689
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0010.000
Research integrity0.0010.000
Insufficient payload (model declined to judge)0.0010.001

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.025
GPT teacher head0.248
Teacher spread0.223 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

Study designBench or experimental
Domainnot available
GenreOther

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations29
Published2017
Admission routes1
Has abstractyes

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