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Record W2070514156 · doi:10.1155/2013/174834

High Performance PEM Fuel Cell with Low Platinum Loading at the Cathode Using Magnetron Sputter Deposition

2012· article· en· W2070514156 on OpenAlexafffund
Daouda Fofana, Sadesh Kumar Natarajan, Pierre Bénard, Jean Hamelin

Bibliographic record

VenueISRN Electrochemistry · 2012
Typearticle
Languageen
FieldEngineering
TopicFuel Cells and Related Materials
Canadian institutionsUniversité du Québec à Trois-Rivières
FundersNatural Sciences and Engineering Research Council of Canada
KeywordsPolytetrafluoroethylenePlatinumCathodeMicroporous materialMaterials scienceNafionProton exchange membrane fuel cellCyclic voltammetryElectrolyteCarbon fibersChemical engineeringSputter depositionLimiting currentComposite materialAnalytical Chemistry (journal)Deposition (geology)SputteringElectrodeElectrochemistryThin filmChemistryNanotechnologyChromatographyFuel cellsCatalysisOrganic chemistry

Abstract

fetched live from OpenAlex

Platinum cluster formations have been investigated as a way to reduce the amount of Pt at the cathode of polymer electrolyte membrane fuel cells. One, two, and three layers of Pt (0.05 mg/cm2) sputtered directly on microporous layers of gas diffusion layers with and without interfacial carbon-Nafion layers and carbon-polytetrafluoroethylene (CPTFE) layers have been used as a cathode. Comparison with experimental results had showed that the best performance was obtained with three layers of Pt sputtered on carbon-Nafion containing 34.8 wt.% of Nafion and sputtered carbon-polytetrafluoroethylene containing 16.9 wt.% of polytetrafluoroethylene. High limiting current densities (>1.1 A/cm2) have been reached with cathode Pt loading as low as 0.05 mg/cm2. SEM imagery and cyclic voltammetry characterization have been performed to consolidate this study. High Pt utilization can be showed by this method. The factor influencing Pt utilisation in the oxygen reduction reaction is intrinsically related to Pt clusters formation and helps in enhancing the PEMFC performance with low Pt loading.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.001
Threshold uncertainty score0.003

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0010.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0010.000
Research integrity0.0010.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.003
GPT teacher head0.165
Teacher spread0.162 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations29
Published2012
Admission routes2
Has abstractyes

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Same venueISRN ElectrochemistrySame topicFuel Cells and Related MaterialsFrench-language works237,207