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Record W2071391316 · doi:10.1029/2009jd012654

The photochemistry of carbon monoxide in the stratosphere and mesosphere evaluated from observations by the Microwave Limb Sounder on the Aura satellite

2010· article· en· W2071391316 on OpenAlexaff
K. Minschwaner, G. L. Manney, N. J. Livesey, H. C. Pumphrey, Herbert M. Pickett, L. Froidevaux, A. Lambert, M. Schwartz, P. F. Bernath, Kaley A. Walker, C. D. Boone

Bibliographic record

VenueJournal of Geophysical Research Atmospheres · 2010
Typearticle
Languageen
FieldEarth and Planetary Sciences
TopicAtmospheric Ozone and Climate
Canadian institutionsUniversity of TorontoUniversity of Waterloo
FundersNatural Environment Research CouncilSight Research UK
KeywordsMicrowave Limb SounderStratosphereAtmospheric sciencesMesosphereEnvironmental scienceLatitudeCarbon monoxideTrace gasMesopauseAltitude (triangle)PhotochemistryChemistryGeologyPhysicsAstronomy

Abstract

fetched live from OpenAlex

The photochemical production and loss rates for carbon monoxide (CO) in the stratosphere and mesosphere are evaluated using measurements from the Aura Microwave Limb Sounder (MLS) and the Atmospheric Chemistry Experiment‐Fourier Transform Spectrometer (ACE‐FTS). The distributions of reactive trace gases involved in the photochemistry of CO, including OH, CH 4 , O( 1 D), Cl, as well as temperatures for calculating reaction rates, are either directly observed or constrained from observations. We map the CO net production and loss as a function of pressure (10–0.02 hPa, about 30–75 km altitude), latitude (approximately ±70°), and season. The results indicate that photochemical loss dominates over production for nearly all conditions considered here. A minimum photochemical loss lifetime of about 10 days occurs near the 2 hPa pressure level, and it follows the region of maximum sunlight exposure. At high latitudes during winter, the CO lifetime is generally longer than 30 days. Time scales become much shorter in spring, however, when CO lifetimes can be 15–20 days poleward of 60° latitude in the upper stratosphere. On the basis of these results, CO is a suitable tracer during autumn to spring above the 0.1 hPa pressure level but not in the upper stratosphere near 1 hPa.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.003
metaresearch head score (Gemma)0.001
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Observational · Consensus signal: Observational
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.447
Threshold uncertainty score0.998

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0030.001
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.001
Science and technology studies0.0010.001
Scholarly communication0.0000.000
Open science0.0010.000
Research integrity0.0000.002
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.041
GPT teacher head0.291
Teacher spread0.250 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designObservational
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations59
Published2010
Admission routes1
Has abstractyes

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