Boron Subphthalocyanine Polymers by Facile Coupling to Poly(acrylic acid‐ran‐styrene) Copolymers Synthesized by Nitroxide‐Mediated Polymerization and the Associated Problems with Autoinitiation
Bibliographic record
Abstract
Boron subphthalocyanines (BsubPcs) are macrocyclic aromatic small molecules containing a chelated boron atom. BsubPcs have interesting optoelectronic and physical properties, justifying their use in various organic electronic devices such as organic solar cells and organic light-emitting diodes. However, our group has only recently reported the first incorporation of a BsubPc moiety into a polymer using a two-step post-polymerization procedure. This communication outlines the use of acrylic acid as a method for obtaining carboxylic acid functional copolymers for the facile coupling to BsubPc post polymerization. In addition, the observations and the proposed mechanism of a side product unique to the copolymerization of acrylic acid and styrene due to autoinitiation are presented.
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How this classification was reachedexpand
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.001 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.001 |
| Science and technology studies | 0.001 | 0.001 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.001 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.001 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one teacher head, not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".