Comparative study of the thermodynamic behaviour of the binary mixtures dimethyl carbonate + (benzene, <i>n</i>-heptane, cyclohexane, or toluene)
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Bibliographic record
Abstract
Isobaric molar heat capacities at 288.15, 298.15, and 308.15 K and densities and speeds of sound at 288.15, 293.15, 298.15, and 308.15 K were determined for the dimethyl carbonate + benzene system over the whole composition range and at atmospheric pressure. In addition, speeds of sound at the same temperatures for the dimethyl carbonate + n-heptane system are reported. These experimental data were used to obtain molar volumes, isobaric thermal expansivities, isentropic and isothermal compressibilities, and isochoric molar heat capacities. Excess quantities of the above-mentioned properties were calculated using the Benson and Kiyohara criterion. The thermodynamic behaviour of the dimethyl carbonate + (n-heptane, cyclohexane, benzene, or toluene) systems is comparatively analyzed.Key words: binary mixtures, excess properties, dimethyl carbonate, benzene, hydrocarbon.
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Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.001 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.002 | 0.000 |
| Research integrity | 0.000 | 0.001 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
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