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Record W2073009608 · doi:10.1021/ac025863k

Breath Analysis and Monitoring by Membrane Extraction with Sorbent Interface

2002· article· en· W2073009608 on OpenAlexafffund
Heather Lord, Yunfan Yu, Alina Segal, Janusz Pawliszyn

Bibliographic record

VenueAnalytical Chemistry · 2002
Typearticle
Languageen
FieldEngineering
TopicAdvanced Chemical Sensor Technologies
Canadian institutionsUniversity of Waterloo
FundersNatural Sciences and Engineering Research Council of Canada
KeywordsChemistrySorbentChromatographyPermeationExtraction (chemistry)MembraneBreath gas analysisFlame ionization detectorAnalytical Chemistry (journal)CartridgeGas chromatographyAdsorptionOrganic chemistry

Abstract

fetched live from OpenAlex

An analytical system consisting of a sampling chamber, membrane extraction module, sorbent trap and gas chromatograph with flame ionization or ion mobility detector was used for on-line monitoring of the composition of the last 250 mL portion of human expired breath. The sampling chamber consisted of a tube fitted with check valves on both ends to allow the air to pass through during expiration, but not to return or allow mixing with ambient air. The last portion of breath was held in the chamber at the end of breath expiration. The organic components in the trapped breath were transferred to the carrier gas by permeation through the membrane in the extraction module and were concentrated in the sorbent trap before introduction as a sharp plug on the front of chromatographic column. Moisture in the breath did not penetrate the membrane to a substantial degree. This system was used to investigate presence of acetone as a biologically important marker of human health as well as exposure to volatile compounds.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.001
Threshold uncertainty score0.004

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0010.000
Meta-epidemiology (broad)0.0010.000
Bibliometrics0.0010.001
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0010.000
Insufficient payload (model declined to judge)0.0010.001

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.007
GPT teacher head0.223
Teacher spread0.215 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations156
Published2002
Admission routes2
Has abstractyes

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