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Record W2073909504 · doi:10.1063/1.2919557

Molecular theory of barycentric velocity: Monatomic fluids

2008· article· en· W2073909504 on OpenAlexafffund
Byung Chan Eu

Bibliographic record

VenueThe Journal of Chemical Physics · 2008
Typearticle
Languageen
FieldEngineering
TopicPhase Equilibria and Thermodynamics
Canadian institutionsMcGill University
FundersNatural Sciences and Engineering Research Council of Canada
KeywordsConstitutive equationClassical mechanicsFlow velocityPhysicsBarycentric coordinate systemStatistical mechanicsFluid dynamicsFlow (mathematics)MechanicsThermodynamicsMathematicsGeometry

Abstract

fetched live from OpenAlex

The notion of barycentric velocity appears in irreversible thermodynamics and fluid mechanics, in which it is a field variable obeying the hydrodynamic equations or, more specifically, the momentum balance equation, which is coupled to the rest of hydrodynamic equations. Therefore, its behavior is not known until the hydrodynamic equations are solved for the flow problem of interest. Unlike diffusion fluxes, heat fluxes, or stresses, it does not have its own constitutive relation similar to Fick's law, Fourier's law, and Newton's law of viscosity. In this work, the constitutive equation is derived for it. In parallel to the phenomenological notion of barycentric velocity, the notion of mean fluid velocity appears in statistical mechanics of irreversible dynamic processes according to the theory of Irving and Kirkwood [J. Chem. Phys. 18, 817 (1950)], and plays the same role of the phenomenological counterpart. In this work, we investigate the statistical mechanical meanings of the mean fluid velocity of a fluid in flow beyond its formal connection with the barycentric velocity. We show that it consists of two components; the center-of-gravity velocity of the packet of fluid molecules, which may be identified with the barycentric velocity in the phenomenological theory, and the diffusive contribution of its collective modes relative to the center of gravity. If the fluid is uniform in space or if the packet of fluid mass is rigid, the diffusive component vanishes. The statistical mechanical (molecular theory) formula for the mean fluid velocity provides the constitutive relation for it in terms of density and temperature gradients present in the fluid in flow. The constitutive relation obtained for the mean fluid velocity can be an important component in the theory of transport processes in liquids. Its significance to fluid mechanics is briefly discussed.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.001
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Theoretical or conceptual · Consensus signal: Theoretical or conceptual
GenreCandidate signal: Empirical · Consensus signal: none
Teacher disagreement score0.002
Threshold uncertainty score0.010

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0010.001
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0010.000
Bibliometrics0.0010.001
Science and technology studies0.0010.003
Scholarly communication0.0020.003
Open science0.0010.001
Research integrity0.0010.001
Insufficient payload (model declined to judge)0.0020.001

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.008
GPT teacher head0.193
Teacher spread0.185 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designTheoretical or conceptual
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations17
Published2008
Admission routes2
Has abstractyes

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